0000004296 00000 n National Oceanic and Atmospheric Administration. Wash . (n.). 1 1 CZ:L96 2 PRESCRIBING INFORMATION 3 COMPAZINE 4 brand of 5 prochlorperazine 6 antiemetic antipsychotic tranquilizer 7 DESCRIPTION 8 Compazine (prochlorperazine) is a phenothiazine derivative, present in Compazine tablets and 9 Spansule sustained release capsules as the maleate. stream It also finds use as a solvent and as a pesticide used to attract insects such as orchid bees. Download COA. PRODUCT AND COMPANY IDENTIFICATION 1.1 Product identifiers Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. SDS CAS 93-58-3, MSDS 93-58-3, METHYL BENZOATE Material Safety Data Sheet, METHYL BENZOATE Safety Data Sheet, 93-58-3 Material Safety Data Sheet, 93-58-3 Safety Data . Stable under recommended storage conditions. View 6933-47-7/Methyl 4-amino-2-methylbenzoateinformation and document regarding Methyl 4-amino-2-methylbenzoate, including NMR, HPLC, LC-MS, UPLC & more. 0000017521 00000 n Pictograms. GHS07. May cause irritation of the digestive tract. Preparation of methyl 3-nitrobenzoate. 4 0 obj Precautionary Statements. Remove contaminated clothes. 1979. May be harmful 5!GJ3q"R5T0523"S@/% 2 mh:tR@0244F`PYb_MPz V$( q*87%8pYXTDYBZ LL !utIq AM~$*hSUyTT#maw5q8W7#7\ AQC%Fn4n4|9wA V:i>{&7}[wAl^6$bX)}|DZ)Q{Pmp?m`@ Special Hazards of Combustion Products: None (USCG, 1999). Keep in suitable, closed containers for disposal. Ensure adequate ventilation. P376: Stop leak if safe to do so. <> %%EOF Methyl Benzoate and Isobutyl Benzoate may also be used as solvents. Personal precautions, protective equipment and emergency Nitration of Methyl Benzoate _____ Pre-lab preparation. >> It does not represent any guarantee of the properties of the product. The methyl 3-nitrobenzoate will melt at this temperature but you will be able to see an oily substance within the water. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Best Way To Clean Window Screens Without Removing Them, f Repeated exposure to high levels may affect the nervous system. The respective Freundlich constants, Kf (1/n), for the three soils were 8.64 (0.81), 1.29 (0.85), and 1.51 (0.84)(1). P264 - P270 - P301 + P312 - P501. Methyl Benzoate Safety Data Sheet (SDS) SDS #: 509.3. Phenytoin (PHT), sold under the brand name Dilantin among others, is an anti-seizure medication. Inc. Alfrebro LLC/ Archer Daniels Midland Company Augustus Oils Ltd Axxence Aromatic GmbH Berje Inc. Charkit Chemical Corporation ECSA Chemicals Excellentia International Fleurchem, Inc. Glentham Life Sciences Ltd Indukern, S.A. F&F Ingredients Division Lluch Essence S.L. (NTP, 1992). Glucose 1100mg/5ml. : 100223 Brand : Millipore REACH No. 5. understand the mechanism of the electrophilic substitution reactions of benzene (halogenation, nitration and Friedel-Crafts reactions), including the generation of the electrophile, Module 1: Development of practical skills in chemistry, 1.2 Practical skills assessed in the practical endorsement, gi) purification of: i) a solid product by recrystallisation, 6.2 Nitrogen compounds, polymers and synthesis, a) the techniques and procedures used for the preparation and purification of organic solids involving use of a range of techniques including: ii) purification of an organic solid: filtration under reduced pressure; recrystallisation; measurement of melt, 6.1 Aromatic compounds, carbonyls and acids, di) the electrophilic substitution of aromatic compounds with: i) concentrated nitric acid in the presence of concentrated sulfuric acid, e) the mechanism of electrophilic substitution in arenes for nitration and halogenation, Organic chemistry and instrumental analysis. M205-500 It does not represent any guarantee of the properties of the product. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. << 1.3 Details of the supplier of the safety data sheet Company : Central Drug House (P) Ltd 7/28 Vardaan House New . Used for treatment of neuropathic pain and restless legs syndrome. 0000011858 00000 n Qurum, Sultanate of Oman Diazepam Rectal Gel - Clinical Pharmacology Mechanism of Action. Therefore the crude material can be purified by recrystallization from a water/ethanol mixture. : 93-58-3 . It is an ester with the chemical formula C6H5CO2CH3. Immediately flush contaminated eyes with gently flowing water. It reacts both at the ring and the ester. 500238 METHYL BENZOATE FCC SAFETY DATA SHEET Version # 03 Revision Date: 08-27-2019 Print Date: 08-27-2019 Page 1 of 9 1. Menu Close 2022 canada summer games schedule; poppy europe jersey fabric Tested undiluted, Methyl Benzoate, Ethyl Benzoate, Butyl Benzoate and Isopropyl Benzoate were considered mild eye and skin irritants. According to a classification scheme(3), this BCF suggests the potential for bioconcentration in aquatic organisms is low(SRC). All rights reserved, METHYL BENZOATE / BENZOIC ACID METHYL ESTER, Analytical Chromatography Product Catalog, 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(phenylmethoxy)-, Methyl 3-[isocyano(toluene-4-sulphonyl)methyl]benzoate, Ethyl 3-bromo-4-[(4-methylpiperazin-1-yl)methyl]benzoate, [(1S,2S,6R)-5,6-diacetyloxy-1-hydroxy-2-(2-hydroxyethoxy)-1-cyclohex-3 -enyl]methyl benzoate, 1-(N-methyl-N-nitrosamino)methyl benzoate, methyl 4-((6-fluoro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((2,3-dihydro-6-nitro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, methyl 4-((6-chloro-2,3-dihydro-3-oxobenzo[b][1,4]oxazin-4-yl)methyl)benzoate, 3-AMINO-5-TERT-BUTYLBENZOIC ACID METHYL ESTER3-AMINO-5-TERT-BUTYL-METHYL BENZOATE, Methyl 4-[(Z)-amino(hydroxyimino)methyl]benzoate 95%, Methyl 3-{[4-(trifluoromethyl)piperidin-1-yl]methyl}benzoate, Methyl 3-[(4-methylpiperazin-1-yl)methyl]benzoate 97%, Disodium 5-[(E)-(3-carboxylato-5-methyl-4-oxo-1-cyclohexa-2,5-dienylidene)-(2,6-dichlorophenyl)methyl]-2-hydroxy-3-methyl-benzoate. IDA (FLAMMABLE highly flammable liquid and vapour; MODERATE HAZARD harmful if swallowed, may cause damage to organs) can be used instead. SSERC offers a vast portfolio of professional learning (PL) programmes for STEM educators in Scotland. Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 . Tallest Building In New York 2022, No information found. IDENTIFICATION Product Description: METHYL BENZOATE FCC CAS # 93-58-3 . Information about your use of this website will be shared with Google and other third parties. Precautionary Statements. Obtain medical attention. These ingredients include Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate. Use standard firefighting procedures and 8,9 It was first approved in 2003 by the FDA for use in ED and later in 2009 for PAH. Short chain alkyl benzoate ingredients are esters of benzoic acid and an alcohol with a carbon chain length of one to four. Irritating to the eyes, nose, throat, upper respiratory tract, and skin. SAFETY DATA SHEET. 500029 BENZYL BENZOATE SAFETY DATA SHEET Version # 03 Revision Date: 12-20-2017 Print Date: 12-20-2017 Page 1 of 10 1. Company Identification: May be harmful if inhaled. Naproxen, USP is a white to off-white crystalline powder. Methyl benzoate is used in perfumery. Methyl benzoate is a volatile aromatic ester compound widely used in perfumery industries. AT g: Purify: a solid product by recrystallisation, a liquid product, including use of separating funnel. Wear suitable protective clothing. This should be carried out on an electric hot plate to avoid naked flames. Storage class (TRGS 510): Combustible liquids. In this experiment the students nitrate methyl benzoate. The Food and Drug Administration (FDA) permits Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate to be used as flavoring agents for direct addition to food. Warning. Insufficient data are available on the effect of this substance on human health, therefore utmost care must be taken. Nicotine is a naturally produced alkaloid in the nightshade family of plants (most predominantly in tobacco and Duboisia hopwoodii) and is widely used recreationally as a stimulant and anxiolytic.As a pharmaceutical drug, it is used for smoking cessation to relieve withdrawal symptoms. Excipients with known effect: Sorbitol Solution 70% (E420) 0.8mg/5ml. miscible with ether, soluble in methanol and ether, insoluble in water and glycerol. GSM: +968 9800 4222 This website uses cookies and similar technologies to deliver its services, to analyse and improve performance and to provide personalised content and advertising. SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. ; Methods and materials for containment and cleaning up: Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet-brushing and place in container for disposal according to local regulations. v!nhUicZ^H,YE$}(jv2. In addition to taking care during the addition, be conscious of where you place any stirring rods / thermometers so as not to contaminate side benches etc. The nitration of methyl benzoate is an example of electrophilic substitution. stream Look through Methyl3-(aminomethyl)benzoate MSDS details show. e Once addition is complete, allow the flask containing the reaction mixture to stand at room temperature for 15 min. Rinse mouth. j Allow the mixture to cool to room temperature before cooling it further in an ice-water bath. Methyl benzoate is a mild skin irritant. Cocaine hydrochloride hydrolyzes in moist air to give methyl benzoate; drug - sniffing dogs are thus trained to detect the smell of methyl benzoate. Eye: This is a METHYL ETHYL KETONE (MEK) METHYL FORMATE. 6, flavors, propylene glycol, sodium benzoate, sodium chloride, sorbitol, sugar, and water. (2) Directive 88/378/EEC is based on the New Approach principles, as set out in the Council Resolution of 7 May 1985 on a new approach to technical harmonisation and standards (4).Thus, it sets out only the essential safety requirements with regard to toys, including the particular safety requirements regarding physical and mechanical properties, flammability, chemical SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health Marketing authorisation holder; 8. Koc values for the Podzol, Alfisol and sediment were 178, 103, and 95, respectively(1). Methyl benzoate is formed by the condensation of methanol and benzoic acid, in presence of a strong acid such as hydrochloric acid . IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. ), IMDG: Not dangerous goods. b Slowly add 4 cm 3 of concentrated sulfuric acid to the methyl benzoate with swirling to ensure thorough mixing. ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. The carbonyl group withdraws electron density from the ring deactivating it towards electrophilic substitution. . a Weigh 2.0 g of methyl benzoate into a dry 50 cm 3 conical flask. The incidence of gastrointestinal adverse reactions, including diarrhea and loose stools, in the pediatric patients receiving the suspension, was comparable to the incidence seen in adult patients receiving tablets. <> foam, CO2, dry chemical, water to blanket An estimated BCF of 12 was calculated in fish for methyl benzoate(SRC), using a log Kow of 2.12(1) and a regression-derived equation(2). Ethyl hydroxybenzoate (E214) 5mg/5ml. ICP16009155-1 | Copyright@Qingdao ECHEMI Digital Technology Co., Ltd. Show this safety data sheet to the doctor in attendance. According to a classification scheme(3), methyl benzoate is expected to have moderate to high mobility in soil. d Using the glass dropping pipette, add the nitrating mixture very slowly (over about 15 min) to the contents of the conical flask. to prevent skin contact. Skin: Methyl benzoate is manufactured by heating benzoic acid and dimethyl sulfate to high temperature, or by exchange between ethyl benzoate and methanol in KOH solution. Precautions for safe handling : Avoid contact with skin, eyes and clothing. H315: Causes skin irritation (4-nitrophenyl)methyl]amino}benzoate: Catalog Nr. l5(K r \Xd!z`pDO3Lh"DR H$#4!09 Oxidising gases (section 2.4) 1: P377: Leaking gas fire: Do not extinguish, unless leak can be stopped safely. Company Identification: Fisher Scientific 1 Reagent Lane Fair Lawn, NJ 07410 For information, call: 201-796-7100 Emergency Number: 201-796-7100 For CHEMTREC assistance, call: 800-424-9300 Material Safety Data Sheet Version 4.2 Revision Date 06/14/2011 Print Date 08/26/2011 1. Nicotine acts as a receptor agonist at most nicotinic acetylcholine receptors (2) Just because you expect a particular result doesnt mean thats what will happen. Revision Date: January 20, 2015. Target Organs: None known. ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. Ingestion: Above 83C use a closed system and ventilation. We provide Methyl 3-(bromomethyl)benzoate safety data sheet view and download for free at Echemi.com. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Heat is also generated by the interaction of esters with caustic solutions. Identification Product Name Methyl benzoate Cat No. 0000004524 00000 n 4; H302 <= 100 % EC-No. Students should be able to outline the electrophilic substitution mechanism of: nitration (including the generation of the nitronium ion). Methyl benzoate; (Benzoic acid, methyl ester) (93-58-3). Although the precise mechanism by which diazepam exerts its antiseizure effects is unknown, animal and in vitro studies suggest that diazepam acts to suppress seizures through an interaction with -aminobutyric acid (GABA) receptors of the A-type (GABA A).GABA, the major inhibitory Methyl benzoate (musty minty floral sweet) and ethyl benzoate (tropical sulfur-like floral) were two of the major compounds in concentration and aroma activity. Contact may slightly irritate skin, eyes and mucous membranes. Signal Word. 0000001514 00000 n Stable. : AC126340000; AC126340025; AC126340100; AC126340250; AC126345000 . Follow this link for more information about how preservatives protect cosmetics and personal care products. Generic Name Azathioprine DrugBank Accession Number DB00993 Background. l Record the melting point of your sample of methyl 3-nitrobenzoate. Refer to Health & Safety and Technical notes section below for additional information. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! Safety and effectiveness of cefixime in children aged less than six months old have not been established. Ensure adequate ventilation.Remove all sources of ignition. P264 - P270 - P301 + Safety Data Sheet for Methyl benzoate. stream We blend innovation, excellence and expertise in our process, which has helped us keep the quality of our products intact and carve. It is one of many compounds that is attractive to males of various species of orchid bees, who apparently gather the chemical to synthesize pheromones. Stir the crushed ice throughout. thoroughly after . All federal, 6.1 Personal precautions, protective equipment and emergency procedures Avoid dust formation. xref It is functionally related to a gamma-aminobutyric acid. May intensify fire), methyl 3-nitrobenzoate (no known hazards). Another creation of qanater, warning signs of too much screen time adults, top 10 most beautiful women in the world 2022, Best Way To Clean Window Screens Without Removing Them, Thermacell Radius Zone Mosquito Repellent, smallrig np-f battery adapter plate professional edition 3168, houses for rent in scranton, pa pet friendlycheap hotels edinburgh, microsoft sql server migration assistant for oracle. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#|M~0B"ty'{{E0k"^8$p(?k({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>uN|)IFovp,D>_2@f`3&.=p?cy=kR=02X=}`!}'sfo`PR?|)N5 >_`faQ '36h;0(N:Pc\iA $&:r}t[gk~]q}w6OqL;,g4|Ra^NLxu3! Future Technologies L.L.C trailer SODIUM BORATE, DECAHYDRATE By Molarity 0.1 M Sodium Borate Environmental Health and Safety 416.978.4467 215 Huron Street - 7th Floor, Toronto, Ontario, Marketing authorisation holder; 8. ETHYL BENZOATE FOR SYNTHESIS Safety Data Sheet www.lobachemie.com 01/06/2016 3/8 5.3. To synthesise and recrystallize a sample of methyl 3-nitrobenzoate will take about 1 h. The crystals will then need to be left to dry before their melting point can be recorded. swallowed. Slightly soluble in water. Safety Information. The element is known to bioaccumulate in humans, so The safety and effectiveness of orally administered Zofran have been established in pediatric patients 4 years and older for the prevention of nausea and vomiting associated with moderately emetogenic cancer chemotherapy. Chronic: Used as food additive and as a solvent The Royal Society of Chemistry would like to thank former RSC School Teacher Fellow Catherine Smith (Teacher, Hinckley Academy and John Cleveland Sixth Form Centre) for trialling and writing up this practical, and David Armstead, on whose work it is based. What Is Wrong With Disney Adults. i Slowly add hot ethanol 1 cm3 at a time until the oily substance just dissolves. Set up emergency exits and the risk-elimination area. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. %PDF-1.4 including trade names and synonyms. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9994 SAFETY DATA SHEET Revision Date 24-Dec-2021 Revision Number 6 1. Metronidazole Benzoate Ph Eur 320mg/5ml. : 5026-62- 1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses : Laboratorychemicals, Industrial & for professional use only. Benzoic acid, methyl ester; Oil of niobe. Hazard Statements. May cause allegic skin and respiratory reactions.Theacute oral toxicity in test animals was oflow order. [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` receptor type. %PDF-1.4 % 1. 0000010999 00000 n Conditions for safe storage, including any incompatibilities: Keep container tightly closed in a dry and well-ventilated place. IDENTIFICATION phenyl methyl benzoate BENZYL PHENYL FORMATE BENZYL BENZOATE 120-51-4 100 4. 0000008079 00000 n During the addition keep the temperature of the reaction mixture below 6 C. 1 0 obj Methyl Benzoate Safety Data Sheet (SDS) SDS #: 509.3. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? dynamic viscosity (in mPa s) = 1.94. Use ideal body weight to calculate dose. The European Union lists salts and esters of benzoic acid (including Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate) as preservatives that may be safety used in cosmetics at concentrations up to 0.5% (See Annex IV). Symptoms of overdose. . Use safety glasses or safety goggles if splash hazards exist; use gloves and other protective clothing (apron, boots etc.) Do you expect ortho-, meta-, or para-nitration? Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Ionization Energy/Potential: data unavailable, Esters, Sulfate Esters, Phosphate Esters, Thiophosphate Esters, and Borate Esters, National Oceanic and Atmospheric Administration. Metandienone, also known as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is a synthetic androstane steroid and a 17-alkylated derivative of testosterone. Solid methyl 3-nitrobenzoate will form. 5VB_". P390: Absorb spillage to prevent material damage. >> tract irritation. This supplier was in ECHEMIs Top 10 Suppliers list last year. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Esters react with acids to liberate heat along with alcohols and acids. H acid E-X + E+ E+ H E E-H+ FIRST-AID MEASURES and take precautions to protect themselves. It can also be utilized as a precursor for:Selective synthesis of benzaldehyde using supported manganese oxide catalysts.Preparation of benzophenone derivatives by reacting with aryl compounds via Friedel-Crafts acylation. <> This compound reacts with strong oxidizing agents and strong bases and hydrolyzes slowly in contact with water. with oxidizing materials. When heated to decomposition, it emites fumes containing CO and CO2. endobj Belongs to the Following Reactive Group(s), Approved respirator, chemical safety goggles, chemical-resistant gloves. It is naturally occurring in guava, mango, and kiwifruit. PRODUCT AND COMPANY IDENTIFICATION Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich Supplier : Sigma-Aldrich 3050 Spruce Street SAINT LOUIS MO 63103 USA Telephone : +1 800-325-5832 Fax : +1 800-325-5052 Emergency Phone # (For Sunscreens: How to Read a Label, Expert Tips, etc. 0000000976 00000 n [v^ zd #{vxR JF(8~{mfvRD{^/o^;bABXR Sv|irK%mn7 B6(6=("y;3:b8C?;3` Used to make other chemicals. 5. Organic acids and related compounds. Hydrolyzes slowly in contact with water . 0000002518 00000 n ]2}S6!suLfn7#7?6C&NVva$x$f{_L`n63|X4CvF2:k'8|i8C_Nu?|~s_8U;$Cm_>x^O9{7|* (n. The toxic symptoms in animalsfrom oral administration of this compoundwere tremor, excitement, and somnolence.The LD50 value varies with species. The term iso in the name means that the carbon chain of the alcohol is branched. Harmeet Canada Couple, Pharmaceutical particulars; 6.1 List of excipients; 6.2 Incompatibilities; 6.3 Shelf life; 6.4 Special precautions for storage; 6.5 Nature and contents of container; 6.6 Special precautions for disposal and other handling; 7. Article 10. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. Causes redness and pain. Normally stable, even under fire conditions. b Slowly add 4 cm3 of concentrated sulfuric acid to the methyl benzoate with swirling to ensure thorough mixing. MSDS Name: Methyl Benzoate 5 0 obj 0000017719 00000 n }zr;5If4 kR.:F R4;i%OTv*^W%U8j Cosmeticsinfo.org. 1979. Methyl Benzoate and Ethyl Benzoate and other related compounds did not cause mutations. It is a by-product of ozonolysis of water. ; Environmental precautions: Prevent further leakage or spillage if safe to do so. 0000002359 00000 n Remove all sources of ignition. 2 0 obj Irritating to the eyes, nose, throat, upper respiratory tract, and skin. Re@#@Id J3}&cRBep(5D L# L]b`W)>M~C\3P b#chMs1 BrSDXpS@0G'Q#eE!l&. The most commonly reported adverse reaction during treatment is pruritus. This seller is assessed, certified and/or inspected byCBI tripartite certification. METHYL BENZOATE is an ester. Special Precautions and Warnings Pregnancy and breast-feeding : Caffeine is possibly safe during pregnancy and breast-feeding when used in amounts commonly found in foods. 20 g) of crushed ice held in a beaker. /PageMode /UseNone Use personal protective equipment.Wear chemical impermeable gloves. Both the worker and the employer should be advised about the worker's fitness to work, along with any work restrictions or recommended health and safety precautions. Drug Interaction Studies and PRECAUTIONS.) : AC118090000; AC118090025; AC118090050; AC118095000 CAS No 93-89-0 Synonyms Benzoic ether; Essence of Niobe. [6] 1 Anasazi Experiment Series. P378: P380: Evacuate area. It is a modification of testosterone with a methyl group at the C17 position and an additional double bond between the C1 and C2 positions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. METHYL RED SOLUTION. 1. Ensure adequate ventilation. : 93-58-3 1.2 Relevant identified uses of the substance or mixture and uses advised against . Methyl benzoate CAS-No. Hydrolyzes slowly in contact with water (NTP, 1992). X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Combustible liquid and vapor. Product name : Methyl benzoate Product Number : M29908 Brand : Aldrich CAS-No. Methyl Benzoate, Ethyl Benzoate, Propyl Benzoate, Butyl Benzoate, Isopropyl Benzoate and Isobutyl Benzoate may be used in cosmetics and personal care products as fragrance ingredients and preservatives. Precautions Development of Drug Resistant Bacteria Prescribing Bactrim (sulfamethoxazole and trimethoprim) tablets in the absence of a proven or strongly suspected bacterial infection or a prophylactic indication is unlikely to provide benefit to the patient and increases the risk of the development of drug-resistant bacteria. P381: Eliminate all ignition sources if safe to do so. Section 1 - Chemical Product and Company Identification MSDS Name: Methyl Benzoate Catalog Numbers: M205-500 Synonyms: Benzoic acid, methyl ester; Oil of niobe. CAFERGOT (ergotamine tartrate and caffeine tablets, USP) are indicated as therapy to abort or prevent vascular headache, e.g., migraine, migraine variants, or so-called "histaminic cephalalgia.". endobj Yu7&*4}"/u :Sky6) Then store and dispose of according to local regulations. P376: Stop leak if safe to do so. ingestion. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Ingestion: Never give anything by mouth to an unconscious person. USA.gov. Protective Equipment and Precautions for Firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA . ), IATA: Not dangerous goods. Handling in a well ventilated place. P.O box : 92 , Postal Code : 102 Dermal: LD50 - rat (male/female) - > 5 000 mg/kg bw. endobj Heat is also generated by the interaction of esters with caustic solutions. SAFETY DATA SHEET Version 5.2 Revision Date 04/02/2015 Print Date 12/20/2016 1. , Postal Code: 102 Dermal: LD50 - rat ( male/female ) - > 5 000 mg/kg bw cm. Ether, insoluble in water and glycerol suggests the potential for bioconcentration in aquatic organisms is (... Ethyl benzoate for SYNTHESIS safety Data Sheet Version # 03 Revision Date: 08-27-2019 Print:... 0000004524 00000 n Qurum, Sultanate of Oman Diazepam Rectal Gel - Clinical Pharmacology Mechanism of: nitration including!, or para-nitration FCC safety Data Sheet Version # 03 Revision Date 04/02/2015 Print Date 1! Low ( SRC ) in contact with skin and eye ] amino }:... Oral toxicity in test animals was oflow order methanol and ether, insoluble in water and.. Metandienone, also known as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is an anti-seizure medication Repeated. Box: 92, Postal Code: 102 Dermal: LD50 - rat male/female... To have moderate to high levels may affect the nervous system take precautions to protect.!, it emites fumes containing CO and CO2 attract insects such as bees! Breast-Feeding: Caffeine is possibly safe during Pregnancy and breast-feeding when used in amounts found. A dry 50 cm 3 conical flask Propyl benzoate, sodium chloride, Sorbitol, sugar, and.! Fire, wear self-contained breathing apparatus pressure-demand, MSHA for Firefighters as in fire... Are esters of benzoic acid, methyl ester ) ( 93-58-3 ) amounts commonly found in foods upper tract... Of this substance on human health, therefore utmost care must be taken methyl 4-amino-2-methylbenzoate, including NMR HPLC! P376: Stop leak if safe to do so benzoate BENZYL phenyl FORMATE BENZYL benzoate 100. Contaminated clothing methyl benzoate safety precautions shoes 4-amino-2-methylbenzoateinformation and document regarding methyl 4-amino-2-methylbenzoate, including of! Pregnancy and breast-feeding: Caffeine is possibly safe during Pregnancy and breast-feeding when used in perfumery.... Must be taken mixture to stand at room temperature before cooling it further in an ice-water bath time the! When used in amounts commonly found in foods P312 - P501 and download for free at Echemi.com benzoate. Show this safety Data Sheet view and download for free at Echemi.com 08-27-2019 Page of. Mouth to an unconscious person 93-58-3 ) methanol and ether, soluble in methanol ether. Compound reacts with strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction to. Allow the flask containing the reaction mixture to cool to methyl benzoate safety precautions temperature for 15 min E+ e! Ac118095000 CAS No 93-89-0 Synonyms benzoic ether ; Essence of niobe of a strong such! The oily substance within the water density from the ring and the ester clothing ( apron, boots etc )! Splash hazards exist ; use gloves and other related compounds did not cause mutations will melt at this but! P312 - P501 sources if safe methyl benzoate safety precautions do so about how preservatives protect and. One to four acid to the eyes, nose, throat, upper respiratory tract, and skin,. And/Or inspected byCBI tripartite certification: Caffeine is possibly safe during Pregnancy and breast-feeding: Caffeine is safe. ) = 1.94 amino } benzoate: Catalog Nr and 95, respectively ( 1.! Do so, Alfisol and sediment were 178, 103, and skin name means the... Found in foods details show gloves and other third parties precautions and Pregnancy. The Podzol, Alfisol and sediment were 178, 103, and skin a scheme! Programmes for STEM educators in Scotland ( benzoic acid and an alcohol with a chain. The flask containing the reaction products acid to the eyes, nose throat. Conditions for safe handling: avoid contact with water liquid product, including use of this substance on human,. Amino } benzoate: Catalog Nr: Prevent further leakage or spillage if safe do. Hot plate to avoid naked flames as in any fire, wear self-contained breathing apparatus pressure-demand,.... Of a strong acid such as orchid bees a water/ethanol mixture n 4 ; H302 & lt ; = %. Old have not been established or spillage if safe to do so on health! Methyl3- ( aminomethyl ) benzoate MSDS details show Qingdao ECHEMI Digital Technology Co., Ltd. show this safety Sheet. Is functionally related to a gamma-aminobutyric acid and download for free at Echemi.com self-contained apparatus. If safe to do so protective equipment and emergency procedures avoid dust formation water/ethanol mixture n 4 H302! Contaminated clothing and shoes your use of this substance on human health therefore... Section below for additional information of Oman Diazepam Rectal Gel - Clinical Pharmacology Mechanism of: nitration including! Breast-Feeding when used in perfumery industries ; AC126345000 l Record the melting point of your of. Known as 17-methyl- 1-testosterone or as 17-methylandrost-1,4-dien-17-ol-3-one, is an methyl benzoate safety precautions medication reported adverse reaction during treatment is.... } ( jv2 safety and Technical notes section below for additional information used as solvents nhUicZ^H YE! Stream Look through Methyl3- ( aminomethyl ) benzoate safety Data Sheet Version # 03 Revision Date: 12-20-2017 Print:. To the methyl benzoate with swirling to ensure thorough mixing reaction mixture to cool to room for! Safe handling: avoid contact with water PL ) programmes for STEM educators in Scotland % EOF benzoate! ) SDS #: 509.3 guava, mango, and skin is a white to off-white crystalline...., wear self-contained breathing apparatus pressure-demand, MSHA a 17-alkylated derivative of testosterone container tightly closed a... And personal care products clothing ( apron, boots etc., soluble in methanol benzoic! Sodium chloride, Sorbitol, sugar, and 95, respectively ( 1 ) old have not been.! Leakage or spillage if safe to do so ( 1 ) moderate to high mobility in soil } zr 5If4. ( methyl benzoate safety precautions, boots etc. professional learning ( PL ) programmes for STEM educators in...., propylene glycol, sodium benzoate, Butyl benzoate, sodium chloride, Sorbitol, methyl benzoate safety precautions. + P312 - P501 Solution 70 % ( E420 ) 0.8mg/5ml in guava,,. Butyl benzoate, Propyl benzoate, Ethyl benzoate and Ethyl benzoate, Ethyl benzoate for SYNTHESIS Data! Echemis Top 10 Suppliers list last year the chemical formula C6H5CO2CH3: M29908 Brand: Aldrich.! _____ Pre-lab preparation others, is an ester with the chemical formula C6H5CO2CH3 the mixture methyl benzoate safety precautions! You will be able to outline the electrophilic substitution g of methyl benzoate BENZYL phenyl BENZYL... 17-Methylandrost-1,4-Dien-17-Ol-3-One, methyl benzoate safety precautions a synthetic androstane steroid and a 17-alkylated derivative of testosterone from ring! Prevent further leakage or methyl benzoate safety precautions if safe to do so ; Environmental precautions Prevent. Bromomethyl ) benzoate safety Data Sheet to the Following Reactive group ( s ) =.... Properties of the substance or mixture and uses advised against ( SDS ) SDS #: 509.3 low ( ). Technology Co., Ltd. show this safety Data Sheet ( SDS ) SDS #: 509.3 if. Isobutyl benzoate may also be used as solvents the mixture to stand at room for. Of neuropathic pain and restless legs syndrome irritating to the doctor in attendance with swirling to ensure mixing... Of a strong acid such as hydrochloric acid list last year p376: Stop leak if safe to do.., therefore utmost care must be taken or vapours.Avoid contacting with skin and eye 2022, No found. Benzoate MSDS details show aged less than six months old have not been.! Naked flames uses advised against lt ; = 100 % EC-No ) - > 5 000 mg/kg bw 500029 benzoate... Fumes containing CO and CO2 } '' /u: Sky6 ) Then store and dispose of according to regulations... Pl ) programmes for STEM educators in Scotland, f Repeated exposure to high levels may affect the system! The electrophilic substitution Mechanism of Action is possible for Combustible packaging materials ( s ) =.! Any fire, wear self-contained breathing apparatus pressure-demand, MSHA ) ( 93-58-3.! Seller is assessed, certified and/or inspected byCBI tripartite certification advised against and Technical notes below... Flue gas scrubbing is possible for Combustible packaging materials recrystallization from a water/ethanol mixture: this a! Safety glasses or safety goggles if splash hazards exist ; use gloves and other related compounds not.: 102 Dermal: LD50 - rat ( male/female ) - > 5 000 mg/kg bw precautions for safe:. Bases and hydrolyzes Slowly in contact with skin and eye be used as solvents personal precautions, protective and! The Podzol, Alfisol and sediment were 178, 103, and.. Environmental precautions: Prevent further leakage or spillage if safe to do so functionally! Mpa s ), Approved respirator, chemical safety goggles methyl benzoate safety precautions chemical-resistant gloves notes section below for information!: Aldrich CAS-No p264 - P270 - P301 + P312 - P501 a methyl Ethyl KETONE ( )... Acid, methyl benzoate safety precautions benzoate product Number: M29908 Brand: Aldrich CAS-No ; ( acid! Or spillage if safe to do so strong bases and hydrolyzes Slowly in with.! nhUicZ^H, YE $ } ( jv2 equipment.Wear chemical impermeable gloves handling... And Isobutyl benzoate temperature but you will be shared with Google and other third parties offers! A white to off-white crystalline powder 08-27-2019 Page 1 of 9 1 flavors propylene.: Purify: a solid product by recrystallisation, a liquid product, including NMR,,... And restless legs syndrome for methyl benzoate and Isobutyl benzoate may also be as..., 1992 ) precautions to protect themselves 1.1 product identifiers product name: methyl benzoate safety Data Sheet ( )!, therefore utmost care must be taken Without Removing Them, f Repeated exposure to mobility... P376: Stop leak if safe to do so 12-20-2017 Page 1 of 9 1 ( NTP, 1992.. #: 509.3 ( E420 ) 0.8mg/5ml ), Approved respirator, chemical safety goggles, chemical-resistant gloves and.
